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Comparison of LFP / NMC technologies*

Lithium – Iron – Phosphate (LiFePO4): the chemistry of the industrial and automotive future

The LiFePO4 (LFP) chemistry particularly meets the needs of the industrial sector, thanks to a unique combination of high safety, significant longevity, and moderate energy requirements. It caters to a wide range of applications, from automation, robotics, logistics, construction, agriculture, boating, to electric vehicles, airport vehicles, aerial platforms, and special vehicles.

Exemplary safety and stability

LFP batteries are considered the safest and most stable on the current market. Available in large capacity formats suited to industrial needs, they avoid the multiplication of small cells in parallel, which can compromise system stability and safety.

Remarkable lifespan

Batteries using LFP chemistry offer lifecycles exceeding 3,500 cycles. Equipped with an efficient electronic management system (BMS), they can reach over 4,000 cycles, with future prospects going up to 6,000 cycles and beyond.

Note: a lifecycle does not mean the battery is unusable at the end of this period. Indeed, even after 3,500 cycles, a battery retains about 80% of its capacity, allowing for many secondary uses, particularly in stationary energy storage.

A major ecological advantage: the absence of cobalt

Unlike other lithium chemistries, the LFP battery is cobalt-free, a toxic material with a heavy environmental impact. This feature gives it a considerable ecological advantage, especially as many manufacturers are now trying to reduce cobalt usage.

Significant progress in energy density

A few years ago, the energy density of LFP batteries was low, around 100 Wh/kg, which limited their appeal. Today, this value has almost doubled, reaching 170 Wh/kg, sparking significant renewed interest, particularly in the automotive sector.

Medium-term prospects suggest a density reaching 220 to 230 Wh/kg, making LFP chemistry even more competitive.

Adoption by the automotive industry

This evolution explains why many car manufacturers are reintegrating LFP chemistry into their electric vehicles.

Among them:

  • Tesla, which already uses LFP in its 'standard range', prioritising safety and controlled cost,

  • BYD,

  • Volkswagen,

  • and many other major names in the automotive industry, who see strong future potential in LFP chemistry.

In Summary

AttributeLithium-Iron-Phosphate (LFP)
SafetyVery High
StabilityVery Good
Lifespan> 3,500 cycles, up to 6,000 expected
End-of-life residual capacity~ 80%
Absence of CobaltYes
Energy Density170 Wh/kg today, 220-230 Wh/kg upcoming
Main ApplicationsIndustry, robotics, electric vehicles, storage
LFP chemistry thus establishes itself as a strategic choice in areas where safety, durability, and environmental impact are priorities, while benefiting from constantly improving energy performance.


LFP in a few figures:

Nominal Voltage: 3.2 V

Energy Density: 177 Wh/kg

Volumetric Density: 384 Wh/l

Full Lifecycles: > 4,000

Discharge Rate: 1C to 3C (i.e., 1 to 3 times the nominal capacity)

+ Robustness, Safety, Cycles

-Mass


Nickel – Manganese – Cobalt (LiNixMnyCozO2): the dominant chemistry in the automotive industry

NMC chemistry remains the most used in the automotive sector today, thanks to its high energy density, allowing a large amount of energy to be stored with reduced weight and volume. This feature is essential for maximising the range of electric vehicles.

Main characteristics

  • Specific Energy: 220 – 240 Wh/kg, higher than other lithium chemistries.

  • Lifecycles: around 1,000 cycles under good charge/discharge conditions.

  • Cost: about 20% higher than LFP, mainly due to the presence of cobalt.

Variants of NMC chemistry

The NMC nomenclature indicates the percentage of Nickel, Manganese, and Cobalt in the cathode:

TypeComposition (%)Main characteristic
NMC 111Ni 33.3 – Mn 33.3 – Co 33.3Older version, less used
NMC 622Ni 60 – Mn 20 – Co 20Current standard version
NMC 811Ni 80 – Mn 10 – Co 10Newer, high energy density and reduced cost
  • NMC 811, with high nickel content and low cobalt, allows for increased specific energy while reducing cost.

  • The evolution of NMC chemistry aims to reduce cobalt, a costly and difficult-to-extract element, while maintaining system stability and lifespan.

Innovation prospects

Some companies are already developing NMX cells, completely cobalt-free, paving the way for more economical and ecological batteries without compromising performance.


To summarise:

CriterionLiFePO4 (LFP)LiNMC (NMC)
Nominal Cell Voltage3.2 V3.6 – 3.7 V
Energy Density (Wh/kg)170 – 177 Wh/kg220 – 240 Wh/kg
Volumetric Density (Wh/l)384 Wh/l600 – 650 Wh/l (variable depending on type)
Lifecycles3,500 – 4,000 cycles (up to 6,000 expected with BMS)~1,000 cycles
Recommended Depth of Discharge (DoD)70 – 90%80%
Discharge Rate1C to 3C1C to 2C
SafetyVery high, stable and non-flammable chemistryLess stable than LFP, requires strict BMS protections
CobaltNonePresent (progressive reduction depending on type: NMC 111, 622, 811)
Relative CostLower~20% more expensive than LFP
Typical ApplicationsIndustry, robotics, stationary storage, standard electric vehiclesAutomotive, high-performance vehicles, applications requiring high energy density
Key AdvantagesLong lifespan, safety, high residual capacity, lower cost, absence of cobaltHigh energy density, low weight and volume, maximum vehicle range
DisadvantagesLower energy density than NMC, limited charging below 0°CShorter lifespan, higher cost, presence of cobalt, lower safety



*: The technical information presented in this article is provided for guidance only. It does not replace the official manuals of the manufacturers. Before any installation, handling or use, please consult the product documentation and follow the safety instructions. The site Torque.works cannot be held responsible for inappropriate use or incorrect interpretation of the information provided.